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In principle, the answer is yes but
in practice the effects are very small in most applications
because the concentration of dissolved, NIR-absorbing
matter is very low in the environment. Absorption of
light by materials dissolved in a sample affects the
value of turbidity and SSC indicated by an OBS sensor
because absorption reduces the light energy available
to be scattered by particles as well as the intensity
of scattered light that escapes from the sample. Other
things being equal, absorption by dissolved matter results
in lower scattered light intensity and lower indicated
SSC for an absorbing samples than for non-absorbing
one.

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We
conducted tests with dissolved organic and inorganic
materials to identify the threshold conditions
where OBS function is substantially impaired. We define
substantial as a 10% reduction in indicated turbidity.
OBS sensors operate in the NIR band so they are colorblind.
That is color perceived by an operator has no direct
influence on OBS function, however, color can indicate
the presence of materials that are strongly absorbing
in the operating spectrum. Our inorganic absorber was
a blue, Copper +2 dye with an absorptivity, ε,
of 23 cm-1 M-1 and the organic
dye was a brown, haemin-based compound with an ε
= 1450 cm-1 M-1; see photographs.
The absorptivity indicate that a one-molar solutions
of the compound will have absorption coefficients of
23 and 1450 cm-1 (recall that pure water
has an absorption coefficient of 0.06 cm-1
at 875 nm). It therefore takes a miniscule concentration
of these materials, less than 100 µM l-1,
to strongly affect sample absorbance and SSC. This is
illustrated on the graph, which shows the decline of
OBS response to silt-size clear-plastic sphere with
increasing dye concentration.

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The significance of absorbance depends
on the εvalues of dissolved matter in real water samples
as well as their environmental concentrations. While
ε values for natural and man-influenced waters
are rarely reported, environmental concentration of
like materials are published. Assuming that dissolved
copper and dissolved organic matter, DOM, have ε values
similar to our analogs (they are likely to be considerably
lower), we compare the concentrations of Copper+2 and
Haemin needed to reduce the OBS signals by 10% with
those for copper and DOM in the environment on the bar
chart. This showed that in all but one situation, environmental
concentrations of dissolved matter are at least 100
times lower than the level needed to produce a 10% reduction
in OBS signal. When monitoring runoff from certain activities,
such as mine tailings, the absorption by dissolved material
can depress the turbidity level measure by an OBS sensor.
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Reference:
John Downing and W.E. Asher. The Effects
of Colored Water and Bubbles on the Sensitivity of OBS
Sensors. American Geophysical Union, 1997
Fall Meeting, San Francisco, CA.
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